Emerging deep eutectic solvents for organic contaminant analysis in food and environmental matrices: A review
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초록

Organic contaminants, including pharmaceuticals and personal care products, pesticides, industrial chemicals, and natural toxins, enter the environment and food chain, posing health risks. Their trace-level analysis in complex matrices requires rapid, selective, and preferably green extraction methods. Deep eutectic solvents (DESs) have emerged as attractive alternatives to volatile organic solvents. Recently, “emerging” subclasses of DESs, namely switchable DESs (SDESs), magnetic DESs (MDESs), and supramolecular DESs (SUPRADESs), have expanded the toolbox. SDESs enable disperser-free phase switching, MDESs simplify magnet-assisted phase separation, and SUPRADESs enhance extraction performance through host–guest inclusion. This review discusses their key physicochemical characteristics and representative applications in food and environmental analysis. Limitations (e.g., weak magnetic responsiveness of MDESs), practical considerations (e.g., compatibility with analytical instruments), and future perspectives (e.g., rational solvent design, integration of complementary DES systems) are also outlined to provide guidance for the continued development of emerging DESs in organic contaminant analysis.

키워드

Environmental analysisFood analysisMagnetic deep eutectic solventOrganic contaminantSample preparation methodSupramolecular deep eutectic solventSwitchable deep eutectic solventLIQUID-LIQUID MICROEXTRACTIONSOLID-PHASEPHYSICOCHEMICAL PROPERTIESWATEREXTRACTIONTEMPERATUREMIXTURES
제목
Emerging deep eutectic solvents for organic contaminant analysis in food and environmental matrices: A review
저자
Chen, JingyanBae, BoyeonLee, Jeongmi
DOI
10.1016/j.trac.2025.118547
발행일
2026-02
유형
Review
저널명
TrAC - Trends in Analytical Chemistry
195