Enantioselective Reactions of Redox-Active Esters Catalyzed via Cooperative Photoredox/Chiral Phosphoric Acid Catalysis
  • Moon, Junsoo
  • Lee, Sujin
  • Shin, Eunjoo
  • Kwon, Yongseok
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초록

Redox-active esters have garnered significant interest owing to their bench stability and photochemical reactivity. When combined with photoredox and chiral phosphoric acid catalysis, these esters enable the formation of new carbon-carbon bonds while concurrently inducing chirality. Since the pioneering enantioselective Minisci-type addition reported by Phipps, substantial progress has been achieved in this promising field. This review summarizes the developments and mechanistic insights accumulated over the past decade, offering perspectives on future research directions.

키워드

Asymmetric catalysisChiral phosphoric acidFriedel-Crafts reactionMinisci reactionPhotoredox catalysisRadical reactionRedox-active esterRADICAL REACTIONSALKALOIDSN-(ACYLOXY)PHTHALIMIDESDECARBOXYLATION
제목
Enantioselective Reactions of Redox-Active Esters Catalyzed via Cooperative Photoredox/Chiral Phosphoric Acid Catalysis
저자
Moon, JunsooLee, SujinShin, EunjooKwon, Yongseok
DOI
10.1055/a-2675-3733
발행일
2025-09
유형
Review; Early Access
저널명
Synthesis
57
23
페이지
3554 ~ 3564