Co(III)-Catalyzed C5-H Amination of Thiochromones with Anthranils
  • Lee, Seungyeon
  • Park, Keunju
  • Kim, Yeo Jin
  • Kumar, Anand
  • Min, Jeonghyun
  • ... Kim, In Su
  • 외 3명
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초록

The incorporation of a nitrogen unit into target molecules by generating nitrene species has become a hot topic in modern organic synthesis. In this study, we report a Co(III)-catalyzed C5-H amination of thiochromones with anthranils as aminating surrogates. The significance of this coupling reaction was demonstrated via a broad range of substrates and complete site selectivity. Moreover, post-transformations of synthesized products are described.

키워드

C-H AMINATIONDERIVATIVESARYLATIONCHROMONESIRIDIUMBONDS
제목
Co(III)-Catalyzed C5-H Amination of Thiochromones with Anthranils
저자
Lee, SeungyeonPark, KeunjuKim, Yeo JinKumar, AnandMin, JeonghyunRakshit, AmitavaLee, Joon-HoSingh, PargatKim, In Su
DOI
10.1021/acs.joc.5c03162
발행일
2026-02-06
유형
Article
저널명
Journal of Organic Chemistry
91
5
페이지
2248 ~ 2256