Doping Engineering of Sodium Vanadium Fluorophosphates Cathodes for Sodium-Ion Batteries
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초록

Sodium-ion batteries offer a promising alternative to lithium-ion batteries due to the abundance and low cost of sodium resources. Na3V2(PO4)(2)F-3-yOy (NVPFOy) stands out as a cathode material with high average operating potential (similar to 3.9 V vs Na+/Na), fast Na+ transport, and strong structural stability (minimal volumetric strain of similar to 2%). This review addresses the structural characteristics and charge storage mechanisms of NVPFOy, focusing on charge compensation and Na+/vacancy ordering. It also discusses recent advances in lattice regulation and doping strategies to enhance electrochemical properties. Finally, we highlight challenges and future directions for practical applications, emphasizing the correlation between crystal structure and performance.

키워드

Sodium-ion batteriesSodium vanadium fluorophosphatesCathodesDoping engineeringEnergy storageELECTROCHEMICAL PERFORMANCENANA3V2(PO4)(2)F-3ENERGYSTORAGESUBSTITUTIONELECTRODESFE
제목
Doping Engineering of Sodium Vanadium Fluorophosphates Cathodes for Sodium-Ion Batteries
저자
Kim, RakyungHwang, MinjunPark, Ho Seok
DOI
10.1007/s11814-025-00388-2
발행일
2025-01
유형
Review; Early Access
저널명
Korean Journal of Chemical Engineering
43
1
페이지
57 ~ 77